Publications:

18) F. Kolundzic, G.C. Micalizio, "Allylic Alkylation of Unactivated Allylic Alcohols via Formal Metallo-[3,3]-Rearrangement" J. Am. Chem. Soc. 2007, accepted.

17) H.L. Shimp, G.C. Micalizio, "An Alkoxide-Directed Alkyne-Allene Cross-Coupling for Stereoselective Synthesis of 1,4-Dienes" Chem. Commun. 2007, asap.

16) M. Takahashi, G.C. Micalizio, "Regio- and Stereoselective Cross Coupling of Substituted Olefins and Imines. A Convergent Stereoselective Synthesis of Saturated 1,5-Aminoalcohols and Sunstituted Piperidines"J. Am. Chem. Soc. 2007, 129, 7514-7516.

15) M. McLaughlin, M. Takahashi, G.C. Micalizio, "An Alkoxide Directed Intermolecular [2+2+1] Annulation: A Three-Component Coupling Reaction for the Synthesis of Tetrasubstituted α,β-Unsaturated γ-Lactams" Angew. Chem. Int. Ed. 2007, 46, 3912-3914.

14) H.A. Reichard, G.C. Micalizio, "A Site- and Stereoselective Intermolecular Alkene-Alkyne Coupling Process" Angew. Chem. Int. Ed. 2007, 46, 1440-1443.

13) J.K. Belardi, G.C. Micalizio, "Studies on the Syntheses of Benzoquinone Ansamycin Antibiotics. Syntheses of the C(5) - C(15) Subunits of Macbecin I, Geldanamycin, and Herbimycin A"
Org. Lett. 2006, 8, 2409-2412.

12) J. Ryan, G.C. Micalizio, "An Alkoxide-Directed Carbometalation of Internal Alkynes"
J. Am. Chem. Soc. 2006, 128, 2764-2765.

11) A.B. Bahadoor, G.C. Micalizio, "Studies in Macrolide Antibiotic Synthesis: The Role of Tethered Alkoxides in Titanium Alkoxide-Mediated Regioselective Reductive Coupling Reactions"
Org. Lett. 2006, 8, 1181-1184.

10) H.L. Shimp, G.C. Micalizio, "Group 4 Metals in Polyketide Synthesis: A Convergent Strategy for the Synthesis of Polypropionate-derived (E,E)-Trisubstituted 1,3-Dienes"
Org. Lett. 2005, 7, 5111-5114.

9) A.B. Bahadoor, A. Flyer, G.C. Micalizio, "A Pentenyl Dianion-Based Strategy for Convergent Synthesis of Ene-1,5-diols" J. Am. Chem. Soc. 2005, 127, 3694-3695.

8) J.-N. Heo, G. C. Micalizio, W. R. Roush, "Enantio- and Diastereoselective Synthesis of Cyclic β-Hydroxy Allylsilanes via Sequential Aldehyde γ-Silylallylboration and Ring Closing Metathesis Reactions" Org. Lett. 2003, 5, 1693.

7) G. C. Micalizio, S. L. Schreiber, "An Alkynylboronic Ester Annulation: Development of Synthetic Methods For Application to Diversity-Oriented Organic Synthesis"
Angew. Chem. Int. Ed. 2002, 41, 3272.

6) G. C. Micalizio and S. L. Schreiber, "A Boronic Ester Annulation Strategy for Diversity-Oriented Organic Synthesis" Angew. Chem. Int. Ed. 2002, 41, 152.

5) G. C. Micalizio and W. R. Roush, "Studies on the Synthesis of Pectenotoxin II: Synthesis of a C(11)-C(26) Fragment Precursor via [3+2]-Annulation Reactions of Chiral Allylsilanes"
Org. Lett. 2001, 3, 1949.

4) W. R. Roush, A. N. Pinchuk, G. C. Micalizio, "[(E)-γ-(Dimethylphenylsilyl)-allyl]diisopinocampheylborane: A Highly Enantioselective Reagent for the Synthesis of anti-β-hydroxyallylsilanes" Tetrahedron Lett. 2000, 41, 9413.

3) G. C. Micalizio, W. R. Roush, and A. N. Pinchuk, "Synthesis of the C(29)-C(45) E-F Bis-Pyran Subunit of Spongistatin 1 (Altohyrtin A)" J. Org. Chem. 2000, 65, 8730.

2) G. C. Micalizio and W. R. Roush, "A Three-Component Coupling Strategy for Tetrahydrofuran Synthesis: Application of the Diisopropyl Tartrate Modified (E)-γ-(Dimethylphenylsilyl)allylboronate as an α,γ-Allyl Dianion Equivalent" Org. Lett. 2000, 2, 461.

1) G. C. Micalizio and W. R. Roush, "Towards the Synthesis of Spongistatin 1: Diastereoselective Synthesis of the C(36)-C(45) Subunit" Tetrahedron Lett. 1999, 40, 3351.

In Progress:

H.L. Shimp, A. Hare, M. McLaughlin, G.C. Micalizio, "Formal Metallo-[3,3]-Rearrangement: Cross-Coupling of Allenic Alcohols with Alkynes: Stereodefined Synthesis of Cross-Conjugated Trienes" 2007, submitted.

J.A. Rieger, G.C. Micalizio, "Studies on the Syntheses of Lptomycins: Convergent Formal Total Synthesis of callystatin A" manuscript in progress.